TABLE: Absolute Rate Constants for the Reactions of C6H5 Studied by the CRD Method
Rate constants are given by k = ATBexp (-C/T) in units of cm3/molecule.s.
Reaction | Method | T (K) | A | B | C | |
C6H5 + NO | CRD | 298-500 | 4.47x10-12 | 0 | -433 | |
C6H5 + HBr | CRD | 297-523 | 3.98x10-11 | 0 | 554 | |
C6H5 + DBr | CRD | 298-500 | 4.37x10-11 | 0 | 612 | |
C6H5 + C2H2 | CRD | 297-523 | 3.72x10-13 | 0 | 1,560 | |
= C6H5C2H+H | 300-1500 | 9.50x10-42 | 9.33 | 1,713b | ||
= C6H5C2H2 | 300-1500 | 1.80x10-7 | -1.63 | 2,711b | ||
C6H5 + C2H4 | CRD | 297-523 | 1.20x10-12 | 0 | 2,250 | |
= C6H5C2H3+H | 300-2000 | 1.20x10-22 | 3.50 | 4,200b | ||
= C6H5C2H4 | 300-2000 | 1.50x1017 | -9.3 | 6,640b | ||
C6H5 + O2 | CRD | 298-473 | 1.00x10-11 | 0 | -161 | |
C6H5 + c-C5H10 | CRD | 297-523 | 4.47x10-12 | 0 | 2,039 | |
C6H5 + c-C6H12 | CRD | 297-523 | 7.94x10-12 | 0 | 1,913 | |
C6H5 + c-C7H14 | CRD | 333 | 8.20x10-14 | |||
C6H5 + c-C8H16 | CRD | 333 | 9.00x10-14 | |||
C6H5 + CCl4 | CRD | 297-523 | 2.00x10-12 | 0 | 1,379 | |
C6H5 + i-C4H10 | CRD | 295-501 | 5.01x10-13 | 0 | 1,532 | |
C6H5 + (i-C3H7)2 | CRD | 295-487 | 8.71x10-13 | 0 | 1,007 | |
C6H5 + C8H18 | CRD | 291-496 | 1.12x10-12 | 0 | 428 | |
C6H5 + C6H6 | CRD | 298-495 | 1.35x10-12 | 0 | 2102 | |
C6H5 + H2 | FTIR,PLP/MS | 548-1017 | 9.50x10-20 | 2.43 | 3159 | |
C6H5 + C6H5 | PLP/MS | 300-500 | 2.31x10-11 | 0 | 56 | |
C6H5 + CH4 | PLP/MS | 600-980 | 1.00x10-11 | 0 | 6201 | |
C6H5 + C2H6 | PLP/MS | 565-1000 | 3.47x10-13 | 0 | 2236 | |
C6H5 + neo-C5H12 | PLP/MS | 565-1000 | 3.89x10-13 | 0 | 1925 | |
C6H5 + CH3 | PLP/MS | 300-980 | 3.98x10-13 | 0 | 23 | |
C6H5 + CO | CRD | 295-500 | 1.41x10-12 | 0 | 1507 | |
C6H5 + CH2O | CRD,PLP/MS | 298-1083 | 1.42x10-19 | 2.19 | 19 | |
C6H5 + C7H8 | CRD | 295-495 | 3.47x10-13 | 0 | 1027 | |
C6H5 + C7D8 | CRD | 295-495 | 3.80x10-13 | 0 | 1340 | |
C6H5 + C8H10 | CRD | 295-495 | 2.46x10-13 | 0 | 526 | |
C6H5 + C3H8 | PLP/MS | 567-1051 | 3.25x10-13 | 0 | 1938 | |
C6H5 + n-C4H10 | CRD, PLP/MS | 297-953 | 4.48x10-13 | 0 | 1880 | |
C6H5 + n-C6H14 | CRD, PLP/MS | 298-1038 | 7.99x10-13 | 0 | 1935 | |
C6H5 + n-C8H18 | PLP/MS | 595-978 | 7.14x10-13 | 0 | 1420 | |
C6H5 + CH2CO | CRD | 301-474 | 1.06x10-12 | 0 | 1183 | |
C6H5 + CH3CHO | CRD | 299-501 | 7.80x10-13 | 0 | 951 | |
C6H5 + CH3COCH3 | CRD | 299-451 | 6.97x10-13 | 0 | 955 | |
C6H5 + CD3COCD3 | CRD | 299-451 | 8.47x10-13 | 0 | 1114 | |
C6H5 + C3H6 | CRD | 296-496 | 1.41x10-12 | 0 | 1512 | |
C6H5 + C6H5C2H | CRD | 297-410 | 1.66x10-11 | 0 | 1224 | |
C6H5 + C6H5C2H3 | CRD | 297-410 | 3.31x10-11 | 0 | 1294 | |
C6H5O + NO | CRD | 297-373 | 4.47x10-12 | 0 | -433 |