TABLE: Absolute Rate Constants for the Reactions of C6H5 Studied by the CRD Method

Rate constants are given by k = ATBexp (-C/T) in units of cm3/molecule.s.

Reaction Method T (K) A B C
C6H5 + NO CRD 298-500 4.47x10-12 0 -433
C6H5 + HBr CRD 297-523 3.98x10-11 0 554
C6H5 + DBr CRD 298-500 4.37x10-11 0 612
C6H5 + C2H2 CRD 297-523 3.72x10-13 0 1,560
       = C6H5C2H+H 300-1500 9.50x10-42 9.33 1,713b
       = C6H5C2H2 300-1500 1.80x10-7 -1.63 2,711b
C6H5 + C2H4 CRD 297-523 1.20x10-12 0 2,250
       = C6H5C2H3+H 300-2000 1.20x10-22 3.50 4,200b
       = C6H5C2H4 300-2000 1.50x1017 -9.3 6,640b
C6H5 + O2 CRD 298-473 1.00x10-11 0 -161
C6H5 + c-C5H10 CRD 297-523 4.47x10-12 0 2,039
C6H5 + c-C6H12 CRD 297-523 7.94x10-12 0 1,913
C6H5 + c-C7H14 CRD 333 8.20x10-14
C6H5 + c-C8H16 CRD 333 9.00x10-14
C6H5 + CCl4 CRD 297-523 2.00x10-12 0 1,379
C6H5 + i-C4H10 CRD 295-501 5.01x10-13 0 1,532
C6H5 + (i-C3H7)2 CRD 295-487 8.71x10-13 0 1,007
C6H5 + C8H18 CRD 291-496 1.12x10-12 0 428
C6H5 + C6H6 CRD 298-495 1.35x10-12 0 2102
C6H5 + H2 FTIR,PLP/MS 548-1017 9.50x10-20 2.43 3159
C6H5 + C6H5 PLP/MS 300-500 2.31x10-11 0 56
C6H5 + CH4 PLP/MS 600-980 1.00x10-11 0 6201
C6H5 + C2H6 PLP/MS 565-1000 3.47x10-13 0 2236
C6H5 + neo-C5H12 PLP/MS 565-1000 3.89x10-13 0 1925
C6H5 + CH3 PLP/MS 300-980 3.98x10-13 0 23
C6H5 + CO CRD 295-500 1.41x10-12 0 1507
C6H5 + CH2O CRD,PLP/MS 298-1083 1.42x10-19 2.19 19
C6H5 + C7H8 CRD 295-495 3.47x10-13 0 1027
C6H5 + C7D8 CRD 295-495 3.80x10-13 0 1340
C6H5 + C8H10 CRD 295-495 2.46x10-13 0 526
C6H5 + C3H8 PLP/MS 567-1051 3.25x10-13 0 1938
C6H5 + n-C4H10 CRD, PLP/MS 297-953 4.48x10-13 0 1880
C6H5 + n-C6H14 CRD, PLP/MS 298-1038 7.99x10-13 0 1935
C6H5 + n-C8H18 PLP/MS 595-978 7.14x10-13 0 1420
C6H5 + CH2CO CRD 301-474 1.06x10-12 0 1183
C6H5 + CH3CHO CRD 299-501 7.80x10-13 0 951
C6H5 + CH3COCH3 CRD 299-451 6.97x10-13 0 955
C6H5 + CD3COCD3 CRD 299-451 8.47x10-13 0 1114
C6H5 + C3H6 CRD 296-496 1.41x10-12 0 1512
C6H5 + C6H5C2H CRD 297-410 1.66x10-11 0 1224
C6H5 + C6H5C2H3 CRD 297-410 3.31x10-11 0 1294
C6H5O + NO CRD 297-373 4.47x10-12 0 -433